SOME TRANSITIONAL METAL IONS COMPLEXES WITH 3-{[(E)-(4-FLUOROPHENYL) METHYLIDENE] AMINO} BENZOIC ACID AND ITS MICROBIAL ACTIVITY
AbstractSome transitional metal ions complexes with 3-{[(Z)-(4-hydroxyphenyl) methylidene] amino} benzoic acid with general formula [M(L2)xH2O], [where M = Mn(II),Co(II), Ni(II),Cu(II), Zn(II), Pd(II) and Pt(II)metal ions and L=3-{[(E)-(4-fluorophenyl) methylidene] amino} benzoic acid ] have been synthesized and characterized on the basis of elemental analysis, conductance, magnetic susceptibility, IR, UV-Visible, ESR, X-RD and TGA/DTA. The complexes are covalent in nature with octahedral geometry. The covalency factor (β), bonding parameter were calculated. The dentistry of the complexes was in the range between 1.5 to 1.90 m/dm3 in toluene and the spectral line indicates low crystallinityof the complexes. All the complexes are non-electrolytic in nature. All the complexes are paramagnetic in nature expect Zn(II) complexes indicates slight participation of the 3d electron in bond formation. The ligand and its complexes have been screened for their antimicrobial activity with some bacteria it shows that antibacterial and antifungal activity complexes are more active towards these bacteria than Schiff base
Article Information
18
1757-1766
737KB
1246
English
IJPSR
Manohar V. Lokhande* and Mrityunjay R. Choudhary
Department of Chemistry, Sathaye College, Vile Parle (E), Mumbai- 400 057, Maharashtra, India
manohar2210@gmail.com
20 November, 2013
04 January, 2014
26 March, 2014
http://dx.doi.org/10.13040/IJPSR.0975-8232.5(5).1757-66
01 May, 2014
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